Abstract
The asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an antimony(V) tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. In the complex cation, the SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018 (5) Å from the porphyrin mean plane. The average Sb—N distance is 2.062 (11) Å, while the Sb—Cl distance is 2.355 (1) Å. The SbV atom of the anion is also located on an inversion center. The [SbCl6]− octahedron exhibits rhombic distortion characterized by the Sb—Cl bond lengths [2.311 (3), 2.374 (2) and 2.393 (4) Å]. In the crystal, the cations and anions are linked C—H⋯ Cl hydrogen bonds, forming a layer parallel to (211).
Highlights
SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions
As part of our continuing studies of antimony porphyrin complexes (Soury et al, 2012), we report here the synthesis and crystal structure of the tiltle compound [Sb(tpp)Cl2][SbCl6] which appears to be the eleventh X-ray structure of an antimony porphyrin complex in the literature
Symmetry codes: (ii) −x, −y+1, −z+2; (iii) x, y, z−1
Summary
The asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an antimony(V). Tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of. The SbV atom of the anion is located on an inversion center. The [SbCl6] octahedron exhibits rhombic distortion characterized by the Sb—Cl bond lengths [2.311 (3), 2.374 (2) and 2.393 (4) Å]. The cations and anions are linked C—H Cl hydrogen bonds, forming a layer parallel to (211). Symmetry codes: (i) x; y þ 1; z þ 2; (ii) x; y; z 1
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