Di-μ-chlorido-1:2κ2Cl,2:3κ2Cl-tetrachlorido-1κCl,2κ2Cl,3κCl-bis[N,N′′-bis(2-furylmethylene)diethylenetriamine]-1κ3N,N′,N′′;3κ3N,N′,N′′-tricopper(II)

Abstract

The complete title trinuclear CuII complex, [Cu3Cl6(C14H16N3O2)2], is generated by twofold symmetry with one Cu atom lying on the rotation axis. The central Cu atom adopts a distorted tetra­hedral CuCl4 geometry. The terminal Cu atom is five-coordinated in a distorted square-pyramidal coordination environment consisting of three N atoms of the ligand, one bridging Cl atom and one terminal Cl atom. Inter­molecular C—H⋯Cl hydrogen bonds help to establish the packing.