Abstract
In the title complex, [CuCl2(C14H14N2)], the CuII atom exhibits a very distorted tetrahedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu2+ cation is 81.49 (11)–145.95 (9)°. The chelate ring including the CuII atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl2 plane.
Highlights
Z=2 Mo K radiation = 1.89 mmÀ1 T = 150 K 0.18 Â 0.16 Â 0.10 mm 6451 measured reflections 3189 independent reflections 2256 reflections with I > 2(I) Rint = 0.039
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZS2154)
99.33 (8) 95.98 (9) 145.95 (9) 101.41 (4) 119.2 (3) 127.1 (3) 113.6 (2) 120.0 (3) 112.6 (2) 127.4 (2) 121.5 (3) 119.2 119.2 119.6 (3) 120.2 120.2 118.8 (3) 120.6 120.6 118.8 (3) 120.6 120.6 122.1 (3) 114.1 (3) 123.7 (3) 118.0 (3) 121.0 121.0 supporting information
Summary
Nonius KappaCCD diffractometer Absorption correction: multi-scan (SORTAV; Blessing, 1995) Tmin = 0.725, Tmax = 0.830. Z=2 Mo K radiation = 1.89 mmÀ1 T = 150 K 0.18 Â 0.16 Â 0.10 mm 6451 measured reflections 3189 independent reflections 2256 reflections with I > 2(I) Rint = 0.039. In the title complex, [CuCl2(C14H14N2)], the CuII atom exhibits a very distorted tetrahedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu2+ cation is 81.49 (11)–145.95 (9). The chelate ring including the CuII atom is approximately planar, with a maximum deviation of 0.039 (4) Afor one of the C atoms; this plane forms a dihedral angle of 46.69 (9) with the CuCl2 plane
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