Abstract
The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R 4 2(8) association.
Highlights
The CuII atom in the title compound, [CuCl2(C16H15N3O)]H2O, is N,N0,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry
H atoms treated by a mixture of independent and constrained refinement max = 0.45 e Å3
H atoms treated by a mixture of independent and constrained refinement w = 1/[σ2(Fo2) + (0.0379P)2 + 0.3259P]
Summary
Dichlorido(1-{(E)-[phenyl(pyridin-2-yljN)methylidene]amino-jN}pyrrolidin-2one-jO)copper(II) monohydrate Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, India, bDepartment of Chemistry, University of Malaya, 50603 Kuala
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