Abstract
The title compound, [PdCl2(C23H23NO)]·CH3OH, was obtained by the reaction of 1-(2,6-dimethylphenylimino)-1,2-diphenylpropan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hydroxylimine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex molecule and the uncoordinated methanol molecule are connected via an O—H⋯O hydrogen bond.
Highlights
The title compound, [PdCl2(C23H23NO)]ÁCH3OH, was obtained by the reaction of 1-(2,6-dimethylphenylimino)-1,2diphenylpropan-2-ol and palladium chloride in methanol
The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hydroxylimine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry
The complex molecule and the uncoordinated methanol molecule are connected via an O— HÁ Á ÁO hydrogen bond
Summary
Absorption correction: multi-scan (SADABS; Sheldrick, 2001) Tmin = 0.779, Tmax = 0.901. Refinement R[F 2 > 2(F 2)] = 0.042 wR(F 2) = 0.082 S = 1.01 4166 reflections 280 parameters. 0.25 Â 0.20 Â 0.10 mm 35358 measured reflections 4166 independent reflections 3418 reflections with I > 2(I) Rint = 0.036. The title compound, [PdCl2(C23H23NO)]ÁCH3OH, was obtained by the reaction of 1-(2,6-dimethylphenylimino)-1,2diphenylpropan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hydroxylimine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex molecule and the uncoordinated methanol molecule are connected via an O— HÁ Á ÁO hydrogen bond
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