Abstract
The anion of the title complex, Cs2[PuCl4O2], adopts a pseudo-octahedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetrachloridodioxidoplutonate(VI) anion. Principal bond lengths include Pu—O = 1.752 (3) Å and Pu—Cl = 2.6648 (8) Å.
Highlights
The anion of the title complex, Cs2[PuCl4O2], adopts a pseudo-octahedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane
Charge balance is maintained by two caesium cations per tetrachloridodioxidoplutonate(VI) anion
Los Alamos National Laboratory is operated by Los Alamos National Security, LLC for the US Department of Energy, Nuclear Security Administration (NNSA) under contract number DE-AC52-06NA25396
Summary
Related literature For related literature, see: Hall et al (1966); Watkin et al (1991); Wilkerson et al (2004); Wilkerson et al (2007); Bean et al (2004, 2005); Grenthe et al (2006); Grigoriev et al (2004); Runde et al (2003); Sessler et al (2002)
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