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Abstract
The Cu atom in the title compound, [CuBr2(C7H6N2)4], is surrounded by four N-heterocycles that define an N4 square-planar geometry. The coordination geometry is distorted towards an elongated octahedron owing to the presence of the two Br− anions, which are located at about 3 Å above and below the square plane. There are two independent molecules in the asymmetric unit, each with their Cu atom lying on an inversion centre.
Highlights
The Cu atom in the title compound, [CuBr2(C7H6N2)4], is surrounded by four N-heterocycles that define an N4 squareplanar geometry
The coordination geometry is distorted towards an elongated octahedron owing to the presence of the two BrÀ anions, which are located at about 3 Aabove and below the square plane
There are two independent molecules in the asymmetric unit, each with their Cu atom lying on an inversion centre
Summary
The Cu atom in the title compound, [CuBr2(C7H6N2)4], is surrounded by four N-heterocycles that define an N4 squareplanar geometry. Absorption correction: multi-scan (ABSCOR; Higashi, 1995) Tmin = 0.073, Tmax = 0.668 12 restraints H-atom parameters constrained Ámax = 0.65 e A À3 Ámin = À1.00 e A À3
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