Abstract
In the title compound, [PdBr2(C18H15As)2], the PdII ion resides on a centre of symmetry and is coordinated by two As atoms [Pd—As = 2.4184 (3) Å] and two Br anions [Pd—Br = 2.4196 (3) Å] in a slightly distorted square-planar geometry [As—Pd—Br = 90.12 (1)°]. The crystal packing exhibits weak intermolecular C—H⋯Br interactions.
Highlights
Related literature For similar palladium structures containing triphenylphosphine and bromido moieties, see: Crawforth et al (2005); Stark & Whitmire (1997); Rodriguez et al (2007)
Findings, conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Research Foundation (NRF)
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV2489)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.004 A; R factor = 0.019; wR factor = 0.043; data-to-parameter ratio = 19.4. The crystal packing exhibits weak intermolecular C—HÁ Á ÁBr interactions. Related literature For similar palladium structures containing triphenylphosphine and bromido moieties, see: Crawforth et al (2005); Stark & Whitmire (1997); Rodriguez et al (2007). For the crystal structures of related bromido arsine complexes, see: Singh et al (1999); Phadnis et al (2003a,b). Crystal data [PdBr2(C18H15As)2] Mr = 878.66 Monoclinic, P21=n a = 9.3754 (11) Ab = 19.545 (3) Ac = 9.8151 (13) A = 112.798 (3)
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
