Abstract
The molecule of the title compound, [NiZnBr2(C17H16N2O2)(C6H7N)2], contains a heterodinuclear arrangement. The two metal ions are bridged via phenol O atoms of the propane-1,3-diylbis(nitrilomethylidyne)]diphenolate (salpd2−) ligand. The two bridging O atoms of salpd2− and two Br atoms constitute a distorted tetrahedral coordination environment around the ZnII ion, while the NiII ion has a distorted octahedral coordination environment formed by two O and two N atoms of salpd2− in the equatorial plane and two N atoms of two 4-methylpyridine ligands in the axial positions. In the crystal structure, weak intermolecular C—H...Br hydrogen bonds link the molecules into chains along the c axis. Weak intramolecular C—H...O and C—H...N hydrogen bonds are also present.
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