Abstract
In the title compound, [CuBr2(C8H22N4)], the CuII atom is six-coordinate forming a distorted octahedral complex and is bonded to two axial bromide anions and four equatorial nitrogen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br distances are 2.8616 (17) and 2.9402 (17) Å, thus the six-coordinate Cu complex shows the usual Jahn–Teller distortion. All amine hydrogen atoms participate in either inter- or intramolecular hydrogen bonding to the Br anions.
Highlights
In the title compound, [CuBr2(C8H22N4)], the Cu atom is sixcoordinate forming a distorted octahedral complex and is bonded to two axial bromide anions and four equatorial nitrogen donors
Supplementary data and figures for this paper are available from the IUCr electronic archives
The cell s.u.'s are taken into account
Summary
R factor = 0.071; wR factor = 0.183; data-to-parameter ratio = 20.3. In the title compound, [CuBr2(C8H22N4)], the Cu atom is sixcoordinate forming a distorted octahedral complex and is bonded to two axial bromide anions and four equatorial nitrogen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br distances are 2.8616 (17) and 2.9402 (17) Å, the six-coordinate Cu complex shows the usual Jahn–Teller distortion. All amine hydrogen atoms participate in either inter- or intramolecular hydrogen bonding to the Br anions
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