Diblock and Triblock Copolymers as Nanostructured Precursors to Functional Nanoporous Materials: From Design to Application.

Abstract

Block copolymers have gained tremendous interest from the scientific community in the last two decades. These macromolecular architectures indeed constitute ideal nanostructured precursors for the generation of nanoporous materials meant for various high added value applications. The parallel emergence of controlled polymerization techniques has notably enabled to finely control their molecular features to confer them with unique structural and physicochemical properties, such as low dispersity values (Đ), well-defined volume fractions, and controlled functionality. The nanostructuration and ordering of diblock or triblock copolymers, which can be achieved through various experimental techniques, including channel die processing, solvent vapor or thermal annealing, nonsolvent-induced phase separation or concomitant self-assembly, and nonsolvent-induced phase separation, allows for the preparation of orientated microphase-separated copolymers whose morphology is dictated by three main factors, i.e., Flory-Huggins interaction parameter between constitutive blocks, volume fraction of the blocks, and polymerization degree. This review article provides an overview of the actual state of the art regarding the preparation of functional nanoporous materials from either diblock or triblock copolymers. It will also highlight the major applications of such peculiar materials.