Abstract
1,2-Dibenzoyl- and 1,2-diacetylhydrazines react with cis-dichlorobis(tertiary phosphine)platinum(II) in refluxing ethanol in presence of a base to give [1,2-dibenzoyl- and diacetylhydrazido(2-)- N, O]bis(tertiary phosphine)platinum(II). the dibenzolhydrazido derivative reacts with hydrogen chloride or acetic acid to give back dibenzoylhydrazine; whereas with bromide, dibenzoyldiimine is formed in quantitative yield.
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