Abstract

The title compound, [Ni(N3)2(C5H5N)2], has two half-mol­ecules in the asymmetric unit. One complete molecule is generated by twofold symmetry, the other by inversion. In this mononuclear compound, each NiII atom is coordinated by four N atoms from two pyridine mol­ecules and two azide anions, thereby forming a slightly distorted square planar configuration.

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