Abstract

In the title compound, [Fe(N3)2(C6H6N4)2], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa­hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The FeII cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol­ecule.

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