Abstract

Chirality is conserved in the deprotonation of the complex PdCl2(La) (La = 2-[(N-p-tolylamino)methyl]pyridine; 1a) leading to the folded diastereomer of [PdCl(μ-La-H)]2 (2a), where the p-tolyl groups are syn exo and the same enantiomer of 1a shapes both halves of the amido-bridged dimer. The dimerization of different enantiomers of 1a (R with S), which should lead to the achiral unfolded diastereomer of 2a where p-tolyl groups would arrange anti, is not observed.

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