Abstract
In this report, we present the application of Pudovik reaction in the synthesis of chiral organophosphorus compounds and shown this reaction to be a promising way to enantiopure aminophosphonic acid derivatives. Cyclization reactions are a new, most efficient strategy for stereoselective synthesis of α-aminophosphonates, namely an intramolecular type of interaction of the P(III) atom and an imino group.
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