Abstract

AbstractThe functionalized arylidene bis(3‐arylaminoacrylates) were efficiently prepared by FeCl3 catalyzed one‐pot domino reactions of primary amines, methyl propiolate and aromatic aldehydes. When isatins were utilized under similar conditions, only 2‐oxoindolinyl 3‐arylaminoacrylates were obtained in moderate yields. 1H NMR data and single crystal structures indicated that this reaction has high diastereoselectivity.

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