Abstract
An efficient synthesis of 2,6‐disubstituted‐1,2,3,6‐tetrahydropyridines is reported, featuring a highly diastereoselective palladium‐catalyzed intramolecular allylic amination from non‐activated alcohols. This method allowed a straightforward access to 2,6‐trans‐1,2,3,6‐tetrahydropyridines with de up to 100 % under mild conditions, in moderate to good yields.
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