Abstract
In the thermal rearrangement of allylic trichloroacetimidates 6, no 1,2-asymmetric induction can be observed. Palladium(II) catalyzed, however, the rearrangement takes place at 25 o C and yields diastereoselectively (de≥98%) the anti-1,2-diamines 7. The allylic trichloroacetimidates 6 can easily be prepared starting from α-amino acids
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