Abstract
Pd[(S,S)-Et-FerroTANE](Ph)(I) undergoes diastereoselective phosphetane ring opening with concomitant Pd-to-P phenyl migration on mild heating. Cleavage of the resulting palladacycle with acid yields Pd[FerroCHAIN]I2, whose reaction with PhMgBr leads to facile opening of the second phosphetane ring and isolation of a complex of a novel C2-symmetric ligand with P and C stereocenters.
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