Abstract
Enolates of chiral propionic acid amides were oxidatively dimerized with cupric salts or iodine with high simple as well as induced diastereoselectivity of up to 99:1. Intramolecular coupling of chiral dienolates of 1,7-heptanediamides led to α 1,2-disubstituted cyclopentane and a derivative of 1,2,6,7-cyclodecane tetracarboxylic acid.
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