Abstract
Abstract Two diastereomeric forms of the μ4-oxo-bridged tetranuclear copper(II) complex [Cu4(O)(L)2(Ac)4] (where L = N2,O-donor Schiff-base ligand and Ac = acetate anion), differing for the bridging arrangement of the carboxylate groups, were individually synthesized and structurally characterized. Their formation was rationalized by DFT calculation and their catecholase-like activity was studied.
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