Abstract
In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the FeII cation is coordinated by two N-bonded thiocyanate anions, two N 4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry. The FeII cation is located on a center of inversion and the lattice water molecule on a twofold rotation axis. The thiocyanate anions, the coordinating water molecules and the sulfide ligands occupy general positions. The complex molecules and lattice water molecules are linked into a three-dimensional network by O—H—N and O—H⋯O hydrogen bonds.
Highlights
FeII cation is coordinated by two N-bonded thiocyanate anions, two N4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry
The FeII cation is located on a center of inversion and the lattice water molecule on a twofold rotation axis
The complex molecules and lattice water molecules are linked into a threedimensional network by O—H—N and O—H O hydrogen bonds
Summary
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-EythStrasse 2, 24118 Kiel, Germany. R factor = 0.038; wR factor = 0.090; data-to-parameter ratio = 15.1. FeII cation is coordinated by two N-bonded thiocyanate anions, two N4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry. The FeII cation is located on a center of inversion and the lattice water molecule on a twofold rotation axis. The thiocyanate anions, the coordinating water molecules and the sulfide ligands occupy general positions. The complex molecules and lattice water molecules are linked into a threedimensional network by O—H—N and O—H O hydrogen bonds
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
