Abstract
In the title compound, [Mn(C6H4N5O)2(H2O)2]·2H2O, the MnII ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1-oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry. All the water H atoms are involved in O—H⋯N and O—H⋯O hydrogen bonds with uncoordinated water O atoms and tetrazole N atoms, which link the molecules into a three-dimensional network.
Highlights
MnII ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry
Atoms, which link the molecules into a three-dimensional network
Symmetry codes: (ii) x−1, y, z; (iii) −x+1, y+1/2, −z+1/2
Summary
All the water H atoms are involved in O—H N and O—H O hydrogen bonds with uncoordinated water O atoms and tetrazole N atoms, which link the molecules into a three-dimensional network
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