Abstract

The CoII atom in the mononuclear title complex, [Co(C8H5Cl2O3)2(C3H4N2)2(H2O)2], lies on an inversion center. The CoII atom has an octa­hedral coordination, involving two carboxylate O atoms of two monodentate 2,4-dichloro­phenoxy­acetate ligands, two N atoms of imidazole ligands and two water mol­ecules. Inter­molecular O—H⋯O hydrogen bonds give rise to chains, which are linked by N—H⋯O hydrogen bonds, forming a sheet structure. The mol­ecules are further linked by π–π stacking inter­actions, generating a two-dimensional supra­molecular network.

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