Abstract
The title mononuclear complex, [Zn(C11H7N6)2(H2O)2], is composed of one ZnII ion, two deprotonated ppt ligands [Hppt = 5-(pyrazin-2-yl)-3-(pyridin-4-yl)-1H-1,2,4-triazole] and two coordinating water molecules. The asymmetric unit consists of one half-molecule that is completed by application of a centre of symmetry. The ZnII atom is six-coordinated in an octahedral environment, surrounded by two O atoms in the axial positions and four N atoms in the equatorial plane. Adjacent mononuclear units are further linked via O—H⋯N hydrogen-bonding interactions, forming a two-dimensional network along (100).
Highlights
College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People’s Republic of China
The asymmetric unit consists of one half-molecule that is completed by application of a centre of symmetry
The ZnII atom is six-coordinated in an octahedral environment, surrounded by two O atoms in the axial positions and four N atoms in the equatorial plane
Summary
College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People’s Republic of China. R factor = 0.035; wR factor = 0.100; data-to-parameter ratio = 11.7. The title mononuclear complex, [Zn(C11H7N6)2(H2O)2], is composed of one ZnII ion, two deprotonated ppt ligands [Hppt = 5-(pyrazin-2-yl)-3-(pyridin-4-yl)-1H-1,2,4-triazole]. The asymmetric unit consists of one half-molecule that is completed by application of a centre of symmetry. The ZnII atom is six-coordinated in an octahedral environment, surrounded by two O atoms in the axial positions and four N atoms in the equatorial plane. Adjacent mononuclear units are further linked via O—H N hydrogen-bonding interactions, forming a two-dimensional network along (100)
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