Diaquabis(4,4 ′-bipyridine)copper(II) di( o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu 4(4,4 ′-C 5H 4NC 5H 4N) 4 rhombic grid clathrating guest dichloromethane

Abstract

In the crystal structure of bis(4,4 ′-bipyridine)diaquacopper(II) di( o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4,4 ′-C 5H 4NC 5H 4N) 2(H 2O) 2] ∞ rhombic grids stack over each other 8.16 Å apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu 4(4,4 ′-bpy) 4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water–anion hydrogen bonds [O⋯O=2.766(4); O⋯ N=3.061(4) A ̊ ]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.