Abstract
In the mononuclear title complex, [Co(C9H9O3)2(H2O)2], each CoII atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co—O bond lengths = 2.0487 (9) and 2.1090 (9) Å] and two water molecules [Co—O bond length = 2.0873 (9) Å] in a distorted octahedral geometry. In the crystal structure, intermolecular hydrogen bonds and π–π stacking interactions [centroid–centroid distance between phenyl rings = 3.692 (2) Å] link the molecules into a supramolecular structure.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.002 A; R factor = 0.024; wR factor = 0.066; data-to-parameter ratio = 16.1. Crystal data [Co(C9H9O3)2(H2O)2] Mr = 425.29 Monoclinic, P21=c a = 11.4968 (1) Ab = 7.1557 (1) Ac = 12.0054 (1) A = 109.708 (1)
In the mononuclear title complex, [Co(C9H9O3)2(H2O)2], each CoII atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co—O bond lengths = 2.0487 (9) and 2.1090 (9) A ] and two water molecules [Co—O bond length = 2.0873 (9) A ] in a distorted octahedral geometry
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LX2056)
Summary
Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.002 A; R factor = 0.024; wR factor = 0.066; data-to-parameter ratio = 16.1. Crystal data [Co(C9H9O3)2(H2O)2] Mr = 425.29 Monoclinic, P21=c a = 11.4968 (1) Ab = 7.1557 (1) Ac = 12.0054 (1) A = 109.708 (1)
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