Diaqua(2,6-dioxo-1,2,3,6-tetrahydropyrimidin-3-ide-4-carboxylato-κ2N3,O4)(1,10-phenanthroline-κ2N,N′)manganese(II)

Rentao Wu,Zebao Zheng,Jikun Li,Yanmin Huo

doi:10.1107/s1600536808005230

Rentao Wu, Zebao Zheng + Show 2 more

Open Access

https://doi.org/10.1107/s1600536808005230

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Abstract

The title compound, [Mn(C5H2N2O4)(C12H8N2)(H2O)2], was synthesized by the reaction of manganese(II) acetate and orotic acid in the presence of 1,10-phenanthroline. The crystal structure exhibits intermolecular N—H⋯O and O—H⋯O hydrogen bonds . The Mn coordination environment consists of an N3O3 donor set in an octahedral geometry.

Highlights

The title compound, [Mn(C5H2N2O4)(C12H8N2)(H2O)2], was synthesized by the reaction of manganese(II) acetate and orotic acid in the presence of 1,10-phenanthroline
The Mn coordination environment consists of an N3O3 donor set in an octahedral geometry
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: OM2206)

Summary

Structure Reports Online

Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.004 A; R factor = 0.030; wR factor = 0.072; data-to-parameter ratio = 11.5. The title compound, [Mn(C5H2N2O4)(C12H8N2)(H2O)2], was synthesized by the reaction of manganese(II) acetate and orotic acid in the presence of 1,10-phenanthroline. The crystal structure exhibits intermolecular N—HÁ Á ÁO and O—HÁ Á ÁO hydrogen bonds. The Mn coordination environment consists of an N3O3 donor set in an octahedral geometry. Related literature For biochemical processes, see: Mukhopadhyay et al, (2004); Ren et al, (2005). For bioinorganic and pharmaceutical studies, see: Lieberman et al, (1955). For coordination chemistry and other aspects, see: Darensbourg et al, (1998). For complexes of the orotate ligand, see: Hambley et al, (1995); Nepveu et al, (1995)

Data collection

DÁ Á ÁA

Bruker SMART diffractometer

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