Abstract
The asymetric unit of the title salt, 3CH5N2S+·3Cl−·2CH4N2S, contains two molecules of thiourea, three (diaminomethylidene)sulfonium cations and three chloride anions. The crystal packing is stabilized by N—H⋯Cl, N—H⋯S, S—H⋯Cl and S—H⋯S hydrogen bonds, forming a three-dimensional network.
Highlights
The asymetric unit of the title salt, 3CH5N2S+3Cl2CH4N2S, contains two molecules of thiourea, threesulfonium cations and three chloride anions
The crystal packing is stabilized by N—H Cl, N—H S, S—H Cl and
Symmetry codes: (i) −x+1, y−1/2, −z+1/2; (ii) −x+1, y+1/2, −z+1/2; (iii) x, −y+1/2, z+1/2; (iv) x, −y+3/2, z+1/2; (v) x, y+1, z; (vi) −x, y+1/2, −z+1/2; (vii) x, −y+3/2, z−1/2; (viii) −x, −y+1, −z
Summary
Hydrogen-bond geometry (Å, ). Laboratoire Privé de Cristallographie (L.P.C), Kénitra, Morocco. R factor = 0.026; wR factor = 0.068; data-to-parameter ratio = 16.3. The asymetric unit of the title salt, 3CH5N2S+3Cl2CH4N2S, contains two molecules of thiourea, three (diaminomethylidene)sulfonium cations and three chloride anions. The crystal packing is stabilized by N—H Cl, N—H S, S—H Cl and S—H S hydrogen bonds, forming a three-dimensional network.
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More From: Acta Crystallographica Section E Structure Reports Online
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