Abstract
ABSTRACT Extraction of Am ( III), Pu( IV), U( VI) from nitric acid solutions by dialkyl ( aryl) [ dialkylcarbamoylmethyl] phosphine oxides of different structures has been studied. The nature of substituents at phosphorus and nitrogen atoms and in methylene bridge affects extraction capacity, solubility and selectivity of reagents. The increase in extraction capacity of reagents with respect to Am, U, Pu and decrease in solubility and selectivity at consecutive replacement of alkyl-( or alkoxy-) radicals at phosphorus atom by phenyl ones was found. The advantage of reagents usage with two different radicals one of which is phenyl at phosphorus atom has been shown. The nature of substituent at nitrogen atom affect solubility but does not practically affect extraction capacity of reagent.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
