Abstract
The reaction of potassium fluoride with the corresponding acid chlorides results in the formation of dialkylamido sulfoxylic acid fluorides Alk 2 N-S-F. Stereo- and regioselectivity of dimethylamido and diisopropylamido sulfoxylic acid fluorides addition reactions to the C,C double bond in cyclohexene, 3,4-dihydro-2H-pyrane, and vinyl ethyl ether has been investigated. This reaction is a convenient approach to the β -fluoroalkyl sulfenic acid derivatives.
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