Abstract
The early introduction of clays into continental sandstones has been attributed to mechanical infiltration by percolation of clay-rich surface waters into grain framework or cutans formed from pedogenic processes. The discovery of pedogenic mud aggregates as traction-load mud in ancient fluvial deposits suggests that permeability and porosity of terrigenous sandstones can be influenced at deposition and control early diagenetic patterns. This study compares diagenesis in fluvial (subaerially exposed) sandstones with lacustrine (subaqueous) sandstones in a Triassic–Jurassic continental rift basin (Hartford Basin, Newark Supergroup). Diversity of diagenetic minerals and sequence of diagenetic alteration can be directly related to depositional environment. The fluvial sandstones in the New Haven Arkose, East Berlin Formation, and Shuttle Meadow Formation of the Hartford Basin are dominated by concretionary calcite and early calcite cement, infiltrated clays (illite–smectite), pedogenic mud aggregates (smectite and illite–smectite), grain coating clays (illite/hematite, illite–chlorite/hematite), quartz overgrowths, late stage carbonate cements (calcite, ferroan calcite), pore-filling clays (illite, kaolinite with minor amounts of smectite, smectite–chlorite, illite–smectite) and hematite. However, pedogenic processes in these fluvial sandstones retarded the development of quartz and feldspar overgrowths, and carbonate authigenesis, as well as the quality of diagenetically enhanced porosity. Dark gray–black lacustrine (subaqueous) sandstones and mudrocks in the East Berlin and Shuttle Meadow Formations are dominated by pyrite, concretionary dolomite and early dolomite cement, radial grain coating clays (smectite–chlorite, illite–smectite), late stage carbonate cements (dolomite, ferroan dolomite, ankerite), albite and pore-filling clays (smectite–chlorite, illite–smectite, illite–chlorite). Clay minerals exist as detrital, mechanically infiltrated, and neoformed clay. The fluvial sandstones in the New Haven Arkose are dominated by illite. The East Berlin and Shuttle Meadow Formations are dominated by illite in the fluvial sequences and smectite–chlorite and illite–smectite in the lacustrine sandstones. Dolomite, ferroan dolomite, and ankerite are restricted to lacustrine sandstones, whereas calcite and ferroan calcite to fluvial sandstones. Albite predominantly precipitated in lacustrine rather than fluvial environments through intergranular dissolution of plagioclase by acidic meteoric water, dissolution of unstable mafic minerals, and sodium-rich brines and evaporites developed from groundwater. Albitization and carbonate cementation are the most pronounced late stage diagenetic processes affecting both types of Hartford sandstones.
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