Diacetato-κO;κ2O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N2,N1,N6)manganese(II) monohydrate

Abstract

The MnII ion in the title compound, [Mn(CH3CO2)2(C18H12N6)(H2O)]·H2O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol­ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water mol­ecules are linked by inter- and intra­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network.