Abstract
AbstractThree copper(II) complexes with a binucleating N2O donor ligand, [Cu2(L1)(μ2‐pz)(CH3COO)2] (1), [Cu4(L1)2(μ4‐O)(μ2‐CH3COO)2(μ1,1‐N3)(N3)] (2), and [Cu2(L2)(μ1,1‐N3)(μ1,3‐N3)2]∞ (3) [pz = pyrazolato, HL1 = 2,6‐bis(morpholinomethyl)‐4‐tert‐butylphenol and HL2 = 2,6‐bis(morpholinomethyl)‐4‐methylphenol] have been synthesized and characterized by elemental analysis, FTIR and UV/Vis spectroscopy, and X‐ray crystallography. X‐ray crystallographic studies revealed that a series of di‐, tetra‐, and polynuclear complexes have been formed by varying the bridging ligand, counteranion, and reaction conditions. These show effective catalytic properties for the hydrogen peroxide oxidation of toluene and benzene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.