Abstract
A series of neutral square planar rhodium(I) dicarbonyls containing singly charged bidentate ligands (salicylaldoxime, α-benzoinoxime, α-furildioxime, α-benzildioxime, dimethylglyoxime, cupferron) has been prepared from three sources: (i) tetracarbonyl-μμ′-dichlorodirhodium(I), (ii) solutions of hydrated rhodium chloride in DMF held under reflux and (iii) a carbonylated solution of hydrated rhodium chloride in boiling absolute alcohol. These dicarbonyls react with triphenylphosphine,-arsine and -stibine to yield monocarbonyl derivatives. The monocarbonyls form 1 : 1 adducts with TCNE. All complexes have been characterized by elemental analysis, i.r. and uv-visible spectra.
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