Di-μ2-chlorido-bis-{chlorido-[2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-κ3 N 2,N 1,N 6]nickel(II)}.

Kwang Ha

doi:10.1107/s2414314621000936

Abstract

In the title compound, [Ni2Cl4(C18H12N6)2], the NiII ions are hexa-coordinated in a distorted octa-hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl- anions in a meridional geometry. The two NiII ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni2Cl2 ring.

Highlights

In the title compound, [Ni2Cl4(C18H12N6)2], the NiII ions are hexa-coordinated in a distorted octahedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three ClÀ anions in a meridional geometry
The two NiII ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex
A crystallographic centre of inversion is located at the centroid of the Ni2Cl2 ring

Summary

Kwang Ha*

In the title compound, [Ni2Cl4(C18H12N6)2], the NiII ions are hexa-coordinated in a distorted octahedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three ClÀ anions in a meridional geometry. The two NiII ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni2Cl2 ring

Structure description

DÁ Á ÁA

Data collection Diffractometer Absorption correction

Kwang Ha

Data collection

Special details