Abstract
In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the TiIV atom in the centrosymmetric complex has a distorted octahedral N2O4 coordination environment and is linked via two μ2-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N′-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to [100], forming channels in which the solvent chloroform molecules are located. C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing.
Highlights
Structure ReportsGory 1/3, Moscow 119991, Russian Federation, and bInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow
In the title compound, [Ti2(C16H14N2O2)2O2]2CHCl3, the TiIV atom in the centrosymmetric complex has a distorted octahedral N2O4 coordination environment and is linked via two 2-oxido bridges into a dinuclear centrosymmetric complex, with a Ti Ti separation of 2.7794 (8) Å
For general background to the chemistry of titanium complexes based on salen-type ligands, see: Gupta & Sutar
Summary
Gory 1/3, Moscow 119991, Russian Federation, and bInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
