Di-μ-methoxo-bis[aquadimethoxonitrosylmolybdenum(II)

Abstract

The title complex, [Mo2(CH3O)6(NO)2(H2O)2], is a pseudocentrosymmetric dimer. The MoII centres are bridged by two methoxo groups and adopt distorted octa­hedral geometries. The crystal structure exhibits two intra­molecular O—H⋯O contacts (O⋯O < 3.0 A) between coordinated water mol­ecules and methoxo groups. One H atom of each water mol­ecule is disordered equally over two sites.