Abstract
The title compound, [Sn2(CH3O)2Cl6(C3H7NO)2], contains two hexacoordinated SnIV atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn2O2 ring. The other sites of the distorted octahedral coordination geometry of the SnIV atom are occupied by three Cl atoms and one O atom from a dimethylformamide molecule. The complex molecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supramolecular network parallel to (10).
Highlights
The title compound, [Sn2(CH3O)2Cl6(C3H7NO)2], contains two hexacoordinated SnIV atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn2O2 ring
The other sites of the distorted octahedral coordination geometry of the SnIV atom are occupied by three Cl atoms and one O atom from a dimethylformamide molecule
The complex molecules are connected by weak C—H Cl hydrogen bonds into a twodimensional supramolecular network parallel to (101)
Summary
R factor = 0.044; wR factor = 0.117; data-to-parameter ratio = 18.5. Symmetry code: (i) x þ 2; y; z þ 1. The title compound, [Sn2(CH3O)2Cl6(C3H7NO)2], contains two hexacoordinated SnIV atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn2O2 ring. The other sites of the distorted octahedral coordination geometry of the SnIV atom are occupied by three Cl atoms and one O atom from a dimethylformamide molecule. The complex molecules are connected by weak C—H Cl hydrogen bonds into a twodimensional supramolecular network parallel to (101)
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