Abstract

The title compound, [BiNaI4(C12H8N2)3], contains a bimetallic neutral cluster, with the metal atoms bridged by two iodide ions. The NaN4I2 coordination is irregular and the BiN2I4 coordination is distorted octa­hedral. A number of π–π stacking inter­actions involving the phenanthroline rings help to establish the crystal packing.

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