Abstract
The title compound, [Zr2(C18H15OSi)6(OH)2(H2O)2]·C7H8, is a dimeric ZrIV compound. The asymmetric unit consists of two half-molecules of the complex and a toluene solvent molecule. The zirconium centres are bridged by two μ-hydroxo ligands. Each Zr is octahedrally coordinated by the hydroxo groups, three triphenylsilanolato groups and an additional water ligand. The centres of both Zr2O2 rings are located on crystallographic centres of inversion. The two independent monomeric units differ significantly with respect to the Zr—O—Si bond angles which is most probably due to the high steric demands of three triphenylsilanolato ligands.
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