Abstract

The title compound, [Zr2Cl8(C6H6ClN)2], is centrosymmetric. Each ZrIV ion has distorted octahedral coordination geometry, formed by one N atom from a 4-chloroaniline ligand, three terminal Cl− ions and two bridging Cl− ions. The Zr—μ-Cl bond distances are much longer than the other Zr—Cl bond distances.

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