Abstract

The structure of [Rh 2 Cl 2 (C 8 H 12 ) 2 ] has been redetermined. The precision of this structure determination compared with other published data shows an improvement such that average bond distance and angle e.s.d.'s are smaller by a factor of two. The bond distances in the cis,cis-1,5-cyclooctadiene ring are compared to those of analogous compounds in the Cambridge Structural Database. The title compound has no molecular symmetry; the cis,cis-1,5-cyclooctadiene rings each have a boat conformation showing C 2v symmetry

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