Abstract
In the crystal structure of the title complex, [Zn2Cl4(C12H8N2)2], each of the two five-coordinated ZnII atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal structure is stabilized by C—H⋯Cl interactions. There is intermolecular π–π stacking between adjacent phenanthroline ligands, with a centroid–centroid distance of 3.151 (3) Å.
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