Abstract
The molecular structure of the title compound, [Ti2Cl2(C6H18NSi2)4], shows a binuclear motif of TiIIIatoms, formulated as [Ti(μ-Cl)(N(SiMe3)2)2]2, with two μ-Cl atoms bridging two ((Me3Si)2N)2Ti moieties. The coordination environment of both central TiIIIatoms is distorted tetrahedral, with a nearly planar four-membered Ti2Cl2core [Ti—Cl—Ti—Cl = 2.796 (15)°].
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