Abstract
In the title compound, [Cu2Cl2(C10H12NO3)2]·CH3OH, each of the two CuII atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intramolecular O—H⋯O hydrogen bonds occur. In the crystal, O—H⋯O hydrogen bonds join the components into a chain extending along the a axis.
Highlights
In the title compound, [Cu2Cl2(C10H12NO3)2]CH3OH, each of the two CuII atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands
The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry
An approximate treatment of cell esds is used for estimating esds involving l.s. planes
Summary
R factor = 0.041; wR factor = 0.092; data-to-parameter ratio = 13.3. In the title compound, [Cu2Cl2(C10H12NO3)2]CH3OH, each of the two CuII atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intramolecular O— H O hydrogen bonds occur. In the crystal, O—H O hydrogen bonds join the components into a chain extending along the a axis. Hydrogen-bond geometry (Å, ). Symmetry codes: (i) x þ 12; y; z þ 12; (ii) x 12; y; z þ 12.
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