Abstract

The title binuclear complex, [Nd2(μ-C2H3O2)2(NCS)4(C5H5NO)2(H2O)6], lies about an inversion centre at the centroid of the four-membered Nd2O2 ring, with the two acetate ions acting as bridging ligands. A monodentate pyridine N-oxide ligand, two terminal thio­cyanate groups and three water mol­ecules complete the coordination environments of each nine-coordinate NdIII atom. O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds link the mol­ecules into a three-dimensional network.

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