Abstract

In the binuclear title manganese(II) complex, [Mn2(C2H3O2)2(C10H8N2)4](ClO4)2, the Mn atoms are six-coordinate in a distorted octa­hedral coordination geometry. The two Mn atoms are bridged by two acetate groups to form a dimeric cation. The complex forms chains through π–π stacking inter­actions.

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