Abstract
The title compound, [Cd2(C2H3O2)4(C12H8N2)2], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π–π interaction between stacked phen groups [centroid–centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010).
Highlights
The title compound, [Cd2(C2H3O2)4(C12H8N2)2], consists of dimeric units built up around a crystallographic symmetry centre
Each cadmium(II) unit is chelated by a 1,10phenanthroline group and two acetate ligands, one of which acts as a bridge, linking both seven-coordinated cadmium(II) centres
The crystal structure is governed by a single – interaction between stacked phen groups
Summary
Rint = 0.020 a Universidad Nacional de la Patagonia, Sede Trelew, 9100 Trelew, Chubut, Argentina, bCenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina, c. Departamento de Fısica, Facultad de Ciencias Fısicas y Matemáticas, Universidad de Chile and CIMAT, Casilla 487-3, Santiago de Chile, Chile, and eDepartamento de Fısica, Comisión Nacional de Energıa Atómica, Buenos Aires, Argentina. R factor = 0.024; wR factor = 0.065; data-to-parameter ratio = 15.9. The title compound, [Cd2(C2H3O2)4(C12H8N2)2], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10phenanthroline (phen) group and two acetate ligands, one of which acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single – interaction between stacked phen groups [centroid–centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010)
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